STRUCTURE AND PHOTOCATALYTIC PROPERTIES OF CARBON CATHODE WITH NANOSTRUCTURED THIN-FILM MOSX/WS2/WSE2 COATING FOR HYDROGEN PRODUCTION
https://doi.org/10.56304/S2079562926010367
EDN: NSLVPW
Abstract
Development and application of multilayer semiconductor catalytic nanostructures based on transition metal chalcogenides with a given energy band structure is a promising direction in the hydrogen industry. Electric fields in the contact region of heterojunctions promote separation and accelerated transfer of nonequilibrium light-induced carriers in the volume of photoactive material of nanocatalysts. The paper studies the nanostructure and photocatalytic properties of two-stage MoS2/WS2/WSe2 heterostructures obtained by pulsed laser deposition. A significant increase in the photocurrent in the heterostructure was achieved compared to photocathodes based on individual films included in the heterostructure. The use of highly informative analysis methods (high-resolution transmission electron microscopy, Raman spectroscopy), as well as quantum-chemical calculations using the density functional theory method, allowed us to identify factors that can have an important effect on the functional characteristics of the created heterostructure.
About the Authors
O. V. RubinkovskayaRussian Federation
D. V. Fominski
Russian Federation
R. I. Romanov
Russian Federation
V. Yu. Fominski
Russian Federation
References
1. Grigoriev S.N., Fominski V.Yu., Romanov R.I., Volosova M.A., Shelyakov A.V. // Thin Solid Films. 2015. V. 592. P. 175–182. https://doi.org/10.1016/j.tsf.2015.09.024
2. Taberna P.L., Barros Barbosa J., Balocchi A., Gerber I., Urita K., Barnabé A., Marie X., Chane-Ching J.Y. // J. Chem. Engin. 2021. V. 424. P. 130433. https://doi.org/10.1016/j.cej.2021.130433
3. Yu X., Prevot M.S., Guijarro N., Sivula K. // Nature Commun. 2015. V. 6. P. 7596. https://doi.org/10.1038/ncomms8596
4. Nevolin V.N., Rubinkovskaya O.V., Fominski D.V., Romanov R.I., Fominski V.Yu. // Inorg. Mater.: Appl. Res. 2024. V. 15 (2). P. 251–258. https://doi.org/10.1134/S2075113324020345
5. Bonomo M., Dini D. // Energies. 2016. V. 9. P. 373. https://doi.org/10.3390/en9050373
6. Fominski V., Fominski D., Demin M., Romanov R., Goikhman A. // Nanomaterials. 2023. V. 13. P. 1122. https://doi.org/10.3390/nano1306112
7. Zhang Y., Liu X., Wang Z., Li H., Chen J. // J. Mater. Chem. A. 2020. V. 8. P. 6957–6983. https://doi.org/10.1039/D0TA00556H
8. Lin L., Xing S., Huo J., Zou G., Sheng X., Liu L., Zhou Y.N. // ACS Appl. Mater. Interfaces. 2019. V. 11 (9). P. 9326–9332. https://doi.org/10.1021/acsami.8b20860
9. Scott G.I., Lionti K., Volksen W., Magbitang T.P., Matsuda Y., Dauskardt H.R., Dubois G. // Nature Mater. 2016. V. 15. P. 294–298. https://doi.org/10.1038/nmat4475
10. Kinz-Thompson C.D., Palma M., Pulukkunat D.K., Chenet D., Hone J., Wind S.J., Gonzalez R.L. // ACS Nano. 2013. V. 7 (9). P. 8158–8166. https://doi.org/10.1021/nn403447s
11. Aralekallu S., Lokesh K.S., Singh V. // Fuel. 2024. V. 357. P. 129753. https://doi.org/10.1016/j.fuel.2023.129753
Review
For citations:
Rubinkovskaya O.V., Fominski D.V., Romanov R.I., Fominski V.Yu. STRUCTURE AND PHOTOCATALYTIC PROPERTIES OF CARBON CATHODE WITH NANOSTRUCTURED THIN-FILM MOSX/WS2/WSE2 COATING FOR HYDROGEN PRODUCTION. Nuclear Physics and Engineering. 2026;17(1):37-43. (In Russ.) https://doi.org/10.56304/S2079562926010367. EDN: NSLVPW
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