INFLUENCE OF THERMAL ACTIVATION ON THE ENHANCMENT OF RAMAN SCATTERING SPECTRA OF DIELECRIC MICROSPHERES IN A METALLIC SHELL
https://doi.org/10.56304/S2079562926010422
EDN: RABCQI
Abstract
In this study, the enhancement of Raman scattering spectra (RS) of individual dielectric (polystyrene) microspheres, coated with a thin (10 nm) metallic shell, deposited on silver-coated cover glasses, was investigated. It was found that laser irradiation with a power of 10–20 μW induces thermal activation, which leads to a sharp increase in the intensity of RS spectra, as well as their modification. This effect is irreversible, indicating structural changes in the metallic shell. After thermal activation, it becomes possible to record spectra at significantly lower excitation powers, which substantially enhances the sensitivity of the method.
About the Authors
M. S. ShestopalovaRussian Federation
A. K. Sarychev
Russian Federation
A. V. Ivanov
Russian Federation
I. V. Bykov
Russian Federation
V. A. Oleinikov
Russian Federation
K. E. Mochalov
Russian Federation
References
1. Langer J. et al. // ACS Nano. 2020. V. 14 (1). P. 28–117.
2. Szaniawska A. et al. // Chemsensors. 2022. V. 10 (5). P. 190.
3. Guerra Hernandez L.A. et al. // J. Opt. Soc. Am. B. 2023. V. 40. P. C78–C85.
4. Zeng et al. // J. Phys. Chem. C. 2017. V. 121 (21). P. 11623–11631.
5. Kelley K.L. et al. // J. Phys. Chem. B. 2003. V. 107 (3). P. 668–677.
6. Mochalov K.E. et al. // Ultramicroscopy. 2017. V. 182. P. 118–123.
7. Georgiev D. // Anal. Chem. 2024. V. 96 (21). P. 8492–8500.
8. Sarhan R.M. // Sci. Rep. 2019. V. 9. P. 3060.
9. Taudul B. et al. // J. Phys. Chem. B. 2024. V. 128 (17). P. 4243–4254.
Review
For citations:
Shestopalova M.S., Sarychev A.K., Ivanov A.V., Bykov I.V., Oleinikov V.A., Mochalov K.E. INFLUENCE OF THERMAL ACTIVATION ON THE ENHANCMENT OF RAMAN SCATTERING SPECTRA OF DIELECRIC MICROSPHERES IN A METALLIC SHELL. Nuclear Physics and Engineering. 2026;17(3):521-525. (In Russ.) https://doi.org/10.56304/S2079562926010422. EDN: RABCQI
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