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APPLICATION OF SMALL-ANGLE NEUTRON SCATTERING TO STUDY THE FILLING OF NANOPOROUS MATERIAL WITH A NON-WETTING LIQUID

https://doi.org/10.56304/S2079562926020016

EDN: TEDRGC

Abstract

The small-angle neutron scattering (SANS) method was used to study the ordered structure of the pores of the MSM-41 powder coated with a layer of a hydrophobic substance. The studies were carried out on the YuMO spectrometer of the IBR-2 reactor (JINR, Dubna). The process of filling and leakage of a non-wetting liquid (heavy water) from nanosized pores of the material with a change in external pressure was studied. For this purpose, a stand and a high-pressure chamber were designed and manufactured, allowing measurements to be carried out using the SANS method in the pressure range of 1–1000 atm. The results obtained show that this technique allows studying the process of filling pores with a non-wetting liquid in nanoporous materials.

About the Authors

A. A. Belogorlov
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences; National Research Nuclear University MEPhI (Moscow Engineering Physics Institute); “NIIgrafit” JSC
Russian Federation


Yu. E. Gorshkova
Joint Institute for Nuclear Research
Russian Federation


G. P. Kopitsa
Petersburg Nuclear Physics Institute named after Konstantinov, National Research Centre “Kurchatov Institute”; Institute of Silicate Chemistry, Branch of the National Research Centre “Kurchatov Institute” – PNPI
Russian Federation


A. I. Kuklin
Joint Institute for Nuclear Research
Russian Federation


D. V. Lvov
National Research Nuclear University MEPhI (Moscow Engineering Physics Institute); Institute for Theoretical and Experimental Physics, National Research Centre “Kurchatov Institute”
Russian Federation


P. G. Mingalev
Faculty of Chemistry, Lomonosov Moscow State University
Russian Federation


A. N. Tyulyusov
National Research Nuclear University MEPhI (Moscow Engineering Physics Institute); Institute for Theoretical and Experimental Physics, National Research Centre “Kurchatov Institute”
Russian Federation


References

1. Feigin L.A., Svergun D.I. Structure Analysis by SmallAngle X-Ray and Neutron Scattering. 1987. New York: Plenum Press.

2. Glinka C., Nicol M., Stucky G., Ramli E., Margolese D., Huo Q., Higgins J., Leonowicz M. // J. Porous Mater. 1996. V. 3. P. 93.

3. Ludescher L., Morak R., Balzer C., Waag A.M., Braxmeier S., Putz F., Busch S., Gor G.Y., Neimark A.V., Hüsing N., Reichenauer G., Paris O. // Langmuir. 2019. V. 35. P. 11590.

4. Xu H. // Int. J. Coal Geology. 2020. V. 217. P. 103325.

5. Matovic B., Gorshkova Yu.E., Kottsov S.Yu., Kopitsa G.P., Butulija S., Minović Arsić T., Cvijović-Alagić I. // Diamond Relat. Mater. 2022. V. 121. P. 108727.

6. Suciu C.V., Iwatsubo T., Deki S. // J. Colloid Interface Sci. 2003. V. 259. P. 62.

7. Xu B., Chen X., Lu W., Zhao C., Qiao Y. // Appl. Phys. Lett. 2014. V. 104. P. 203107.

8. Borman V.D., Belogorlov A.A., Tronin V.N. // Colloids Surf. A. 2018. V. 537. P. 540.

9. Esquivel-Castro T.A., Ibarra-Alonso M., Oliva J., Martínez-Luévanos A. // Mater. Sci. Eng. C. 2019. V. 96. P. 915.

10. Hu C., Sedghi S., Madani S.H., Silvestre-Albero A., Sakamoto H., Kwong P., Pendleton P., Smernik R. J., Rodríguez-Reinoso F., Kaneko K., Biggs M.J. // Carbon. 2014. V. 78. P. 113.

11. Belogorlov A., Borman V., Bortnikova S., Tronin V. // J. Phys.: Conf. Ser. 2016. V. 751. P. 012030.

12. Ying J.Y., Mehnert C.P., Wong M.S. // Angew. Chem. Int. Ed. 1999. V. 38. P. 56.

13. Lowell S., Shields J.E., Thomas M.A., Thommes M. Characterization of Porous Solids and Powders: Surface Area, Pore Size and Density. 2004. Dordrecht: Kluwer Academic Publ.

14. Fadeev A.Y. and Eroshenko V.A. // J. Colloid Interface Sci. 1997. V. 187. P. 275.

15. Borman V., Belogorlov A., Grekhov A., Lisichkin G., Tronin V., Troyan V. // J. Exp. Theor. Phys. 2005. V. 100. P. 385.

16. Belogorlov A., Bortnikova S., Mingalev P. // J. Surf. Invest. 2017. V. 11. P. 425.

17. Kuklin A.I., Soloviov D.V., Rogachev A.V., Utrobin P.K., Yu S.K., Balasoiu M., Ivankov O.I., Sirotin A.P., Murugova T.N., Petukhova T.B. et al. // J. Phys: Conf. Ser. 2011. V. 291. P. 012013.

18. Kuklin A., Islamov A.K., Gordeliy V. // Neutron News. 2005. V. 16. P. 16.

19. Soloviev A., Murugova T., Islamov A., Kuklin A. // J. Phys.: Conf. Ser. 2012. V. 351. P. 012027.

20. Ostanevich Y. // Macromol. Symp. 1988. V. 15. P. 91.


Review

For citations:


Belogorlov A.A., Gorshkova Yu.E., Kopitsa G.P., Kuklin A.I., Lvov D.V., Mingalev P.G., Tyulyusov A.N. APPLICATION OF SMALL-ANGLE NEUTRON SCATTERING TO STUDY THE FILLING OF NANOPOROUS MATERIAL WITH A NON-WETTING LIQUID. Nuclear Physics and Engineering. 2026;17(2):324-329. (In Russ.) https://doi.org/10.56304/S2079562926020016. EDN: TEDRGC

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